Ground State Second-order Properties with MP2 and CC2

For closed-shell restricted Hartree-Fock reference states second-order properties for one-electron perturbation can be computed at the MP2 and the CC2 level. For MP2, second-order properties are computed as derivatives of the SCF+MP2 total energy. This approach include the relaxation of the SCF orbitals in the presence of the perturbation and is restricted to the static (i.e. frequency-independent) limit.

For coupled-cluster model CC2, second-order properties can, similar as the first-order properties, calculated in orbital-unrelaxed or orbital-relaxed approach as derivatives of the of the Lagrange functions in Eqs. 9.12 and 9.15. As for MP2, the orbital-relaxed calculations are restricted to the static limit. Frequency-dependent second-order properties as e.g. dipole polarizabilities can be computed with the orbital-unrelaxed approach.

Note that second-order properties are currently not yet available in the MPI parallel version or for spin-component scaled variants of MP2 and CC2. Furthermore, non-abelian point groups are not implemented for second-order properties.

In addition to the standard input, second-order properties require that the
data group for the numerical Laplace transformation `$Laplace`
and that the `sops`

option in the data group `$response` is set.
Frequency-dependent dipole polarizabilities with the CC2 model are obtained with
the input:

$ricc2 cc2 $laplace conv=4 $response sop operators=(diplen,diplen) freq=0.077d0The frequency has to be given in atomic units. Static orbital relaxed polarizabilities are obtained with

$response sop operators=(diplen,diplen) relaxed